Synthesis and characterizaton of silver/silver oxide thin film via chemical bath deposition

Authors

  • T. O. Daniel Alex Ekwueme-Federal University Ndufu-Alike Ikwo
  • U. Nwankwo Alex Ekwueme-Federal University Ndufu-Alike Ikwo

DOI:

https://doi.org/10.31349/RevMexFis.71.011003

Keywords:

Ag/AgO thin films; chemical bath deposition; characterisation; nanoparticle

Abstract

The chemical bath deposition technique was used to deposit Ag/AgO films on a glass substrate using silver nitrate (AgNO3) and triethanolamine (a polymer matrix) as the complexing agent. X-ray diffraction (XRD) was used to study the crystalline structure of the films, scanning electron microscopy (SEM) was used to study the micrograph/morphology, and energy dispersive spectroscopy (EDS) was used for elemental composition analysis. Four peaks at 2θ values of 38.05°, 44.15°, 64.31°, and 77.41° matched the (111), (200), (220), and (311) peaks, respectively, indicating that the obtained films were crystalline. The Ag/AgO films had a relatively low transmittance value of approximately 12% in the wavelength range of 300 to 1100 nm, a band gap energy of less than 2 eV, and a high absorbance of ≥ 80%, suggesting applications in photothermal, photoelectronic devices/systems, architectural coatings, and other areas where spectrally selective films are of interest.

Author Biography

T. O. Daniel, Alex Ekwueme-Federal University Ndufu-Alike Ikwo

PHYSICS (MATERIALS SCIENCE AND ENERGY UNIT), LECTURER/RESEARCHER

References

Y. J. Wang et al., The use of polymer-based nanoparticles and nanostructured materials in treatment and diagnosis of cardiovascular diseases: Recent advances and emerging designs. Progress in Polymer Science, 57 (2016) 153-178

A. G. Niculescu and A. M. Grumezescu, Polymer-based nanosystems-A versatile delivery approach. Materials, 14 (2021) 6812, https://doi.org/10.3390/ma14226812

J. H. Zhang, S. Z. Wang, J. B. Liu, Z. L. Wang, and N. B. Ming, Preparation and absorption properties of polystyrene/Ag/TiO2 multiple coated colloids. Journal of Materials Research, 20 (2015) 965-970

K. Ma, and Z. An, Macromolecular rapid communications. Macromolecular Rapid Communications, 37 (2016) 1632

A. Hammad, M. Abdel-Wahab, and A. Alshahrie, Structural and morphological properties of sputtered silver oxide thin films: The effect of thin film thickness. Digest Journal of Nanomaterials and Biostructures, 11 (2016) 1245-1252

J. Kwon et al., Recent progress in silver nanowire based flexible/wearable optoelectronics. Journal of Materials Chemistry C, 6 (2018) 7445-7461

H. S. Barud et al., Self-supported silver nanoparticles containing bacterial cellulose membranes. Materials Science and Engineering: C, 28 (2008) 515-518

N. Vigneshwaran, R. P. Nachane, P. V. Vardarajan, and R. H. Balasubramanya, A novel one-pot ‘green’ synthesis of stable silver nanoparticles using soluble starch. Carbohydrate Research, 341 (2009) 2012-2018

W. Sun et al., SERS-active Ag-Al alloy nanoparticles with tunable surface plasmon resonance induced by laser ablation. Optical Materials, 96 (2019) 109298, https://doi.org/10.1016/j.optmat.2019.109298

K. Kayed, The optical properties of individual silver nanoparticles in Ag/Ag2O composites synthesized by oxygen plasma treatment of silver thin films. Plasmonics (2020). https://doi.org/10.1007/s11468-020-01169-9

B. El-Ghmari, H. Farah, and A. Ech-Chahad, A new approach for the green biosynthesis of silver oxide nanoparticles Ag2O, characterization and catalytic application. Bulletin of Chemical Reaction Engineering & Catalysis, 16 (2021) 651-660, https://doi.org/10.9767/bcrec.16.3.11577.651-660

T. O. Daniel, U. E. Uno, K. U. Isah, and U. Ahmadu, Optimization of electrical conductivity of SnS thin film of 0.2 < t ≤ 0.4 µm thickness for field effect transistor application. Rev. Mex. Fis., 67 (2021) 263-268

T. O. Daniel, U. E. Uno, K. U. Isah, and U. Ahmadu, Tuning of SnS thin film conductivity on annealing in an open air environment for transistor application. East European Journal of Physics, 2 (2020) 94-103

S. W. Balogun, A. B. Abdulhamid, Y. K. Sanusi, and O. Adedokun, Synthesis and characterization of silver nanoparticlesdoped titanium (IV) oxide thin films. IOP Conference Series: Materials Science and Engineering, 805 (2020) 012034. https://doi.org/10.1088/1757-899X/805/1/012034

R. K. Sharma, et al., Silver nanomaterials: Synthesis and (electro/photo) catalytic applications. Chemical Society Reviews, 50 (2021) 11293, https://doi.org/10.1039/d0cs00912a

M. Li, Y. Wang, Y. Xing, and J. Zhong, P123-assisted preparation of Ag/Ag2O with significantly enhanced photocatalytic performance. Solid State Sciences, 99 (2020) 106062, https://doi.org/10.1016/j.solidstatesciences.2019.106062

L. Gomathi Devi, and R. Kavitha, A review on plasmonic metal-TiO2 composite for generation, trapping, storing, and dynamic vectorial transfer of photogenerated electrons across the Schottky junction in a photocatalytic system. Applied Surface Science, 360 (2016) 601, https://doi.org/10.1016/j.apsusc.2015.11.168

T. O. Daniel, U. E. Uno, K. U. Isah, and U. Ahmadu, Electric double layer field effect transistor using SnS thin film as semiconductor channel layer and honey gate dielectric. East European Journal of Physics, 3 (2019) 71-80

Downloads

Published

2025-01-01

How to Cite

[1]
T. O. DANIEL and U. Nwankwo, “Synthesis and characterizaton of silver/silver oxide thin film via chemical bath deposition”, Rev. Mex. Fís., vol. 71, no. 1 Jan-Feb, pp. 011003 1–, Jan. 2025.