Effect of Cr3+ substitution on magnetic and electrical properties of (Ni0.3Cu0.7) Fe2O4 spinel ferrites
DOI:
https://doi.org/10.31349/RevMexFis.66.573Keywords:
Ferrites, Sol gel, XRD, Dielectric constant, electrical resistivity, magnetic propertiesAbstract
Chromium substituted copper base spinel ferrites (Ni0.3Cu0.7)CrxFe2-xO4 were prepared by Sol-gel method. Structural, magnetic and electrical properties were studied by utilizing X-ray diffractometer, Vibrating sample magnetometer, and precision LCR-meter using lab-tracer software. The X-ray diffraction analysis confirmed the formation of single phase fcc structure of the samples. The lattice constant and crystallite size decreased from 8.37-8.23Å and 53.09-35.36nm respectively with increasing content of Cr3+ ions. From MH loops it was observed that the saturation magnetization decreased and coercivity increased with increasing content of Cr3+ ions. Dc resistivity increased with increase of Cr3+ concentration and decreased with increase in temperature which shows the semiconducting behavior of ferrites. The dielectric constant, dielectric loss and tangent loss decreased with increase of Cr3+ concentration. The dielectric constant follows bilayer Maxwell Wagner model and Koop’s phenomenological theory while ac conductivity increased with increasing frequency following Jonscher’s power law.
References
Rao, CNR and AK Cheetham. "Science and Technology of Nanomaterials: Current Status and Future Prospects." Journal of Materials Chemistry 11, no. 12 (2001): 2887-94.
Ozin, Geoffrey A. "Nanochemistry: Synthesis in Diminishing Dimensions." Advanced Materials 4, no. 10 (1992): 612-49.
Sun, Xiang-Cheng and Xing-Long Dong. "Magnetic Properties and Microstructure of CarbonEncapsulated Ni Nanoparticles and Pure Ni Nanoparticles Coated with NiO Layer." Materials research bulletin 37, no. 5 (2002): 991-1004.
Lu, Lian, ML Sui, and Ke Lu. "Superplastic Extensibility of Nanocrystalline Copper at Room Temperature"Science 287, no. 5457 (2000): 1463-66.
Raj, K, B Moskowitz, and R Casciari. "Advances in FerrofluidTechnology."Journal of magnetism and magnetic materials 149, no. 1-2 (1995): 174-80.
Jian-Ping, Wang and Luo He-Lie. "Preparation and Properties of Pure Nanocomposite FeSiO2 Using the Sol-Gel Method."Journal of magnetism and magnetic materials 131, no. 1-2 (1994): 54-60.
Gleiter, H. "Materials with Ultrafine Microstructures: Retrospectives and Perspectives." Nanostructured materials 1, no. 1 (1992): 1-19.
Weil, L, F Bertaut, and L Bochirol. "PropriétésMagnétiquesEt Structure De La Phase Quadratique Du Ferrite De Cuivre."Journal de Physique et le Radium 11, no. 5 (1950): 208-12.
O’BRYAN, HM. "Jr., HjLevinstein, and Rc Sherwood." J. ApplPhys 37 (1966).
Janicki, J, J Pietrzak, APorȩbska, and J Suwalski. "Mössbauer Study of Copper Ferrites." physica status solidi (a) 72, no. 1 (1982): 95-98.
Mexmain, J. "Copper (Ii) Ferrite." Ann. Chim.(Paris) 4, no. 6 (1969): 429-40.
Villette, Carole, Philippe Tailhades, and Abel Rousset. "Thermal Behavior and Magnetic Properties of Acicular Copper-Cobalt Ferrite Particles."Journal of solid state chemistry 117, no. 1 (1995): 64-72.
Grimbolt, Jean, Léon Gengembre, and Alain D'Huysser. "Xps: A Routine Technique to Characterize Surface of Practical Catalysts?" Journal of Electron Spectroscopy and Related Phenomena 52 (1990): 485-509.
Tang, Xiao-Xia, AManthiram, and JB Goodenough. "Copper Ferrite Revisited." Journal of solid state chemistry 79, no. 2 (1989): 250-62.
Guan, Ying-Hong, Jun Ma, Yue-Ming Ren, Yu-Lei Liu, Jia-Yue Xiao, Ling-qiang Lin, and Chen Zhang. "Efficient Degradation of Atrazine by Magnetic Porous Copper Ferrite Catalyzed Peroxymonosulfate Oxidation Via the Formation of Hydroxyl and Sulfate Radicals." Water research 47, no. 14 (2013): 5431-38.
Ghorpade, Sheetal P, VS Darshane, and Sharad G Dixit. "Liquid-Phase Friedel-Crafts Alkylation Using CuCr2− XFexO4 Spinel Catalysts."Applied Catalysis A: General 166, no. 1 (1998): 135-42.
Mulushoa, S Yonatan, N Murali, M Tulu Wegayehu, SJ Margarette, and K Samatha. "Influence of Cu-Cr Substitution on Structural, Morphological, Electrical and Magnetic Properties of Magnesium Ferrite."Results in physics 8 (2018): 772-79.
Singh, RN, JP Singh, B Lal, and A Singh. "Preparation and Characterization of CuFe2-XCrxO4 (0⩽ X⩽ 1.0) Nano Spinels for Electrocatalysis of Oxygen Evolution in Alkaline Solutions."International journal of hydrogen energy 32, no. 1 (2007): 11-16.
Zhang, XY, J Xu, ZZ Li, WH Qi, GD Tang, ZF Shang, DH Ji, and LL Lang. "Experimental Evidence for the Magnetic Moment Directions of Cr2+ and Cr3+ Cations in the Spinel Ferrites Cux1Crx2Fe3− X1− X2O4." Physica B: Condensed Matter 446 (2014): 92-99.
More, SD, CM Kale, AB Shinde, and KM Jadhav. "Role of Cr 3+ Substitution on Electrical and Dielectric Behavior of Cu-Ferrite Nanoparticles."International Journal of Engineering and Advanced Technology ((IJEAT) ISSN: 2249–8958), Issue-2 3 (2013): 177-80.
Zhang, XY, J Xu, ZZ Li, WH Qi, GD Tang, ZF Shang, DH Ji, and LL Lang. "Experimental Evidence for the Magnetic Moment Directions of Cr2+ and Cr3+Cations in the Spinel Ferrites Cux1Crx2Fe3− X1− X2O4." Physica B: Condensed Matter 446 (2014): 92-99.
Baykal, A, S Guner, H Gungunes, KM Batoo, Md Amir, and A Manikandan. "Magneto Optical Properties and Hyperfine Interactions of Cr 3+ Ion Substituted Copper Ferrite Nanoparticles." Journal of Inorganic and Organometallic Polymers and Materials (2018): 1-12.
Shinde, BajarangLaxman, LaxmanAppaDhale, Venkat S Suryavanshi, and KishanShankarraoLohar. "Preparation and Characterization of Chromium-Doped Ni-Cu-Zn Nano Ferrites."ActaChimicaSlovenica 64, no. 4 (2017): 931-37.
Mulushoa, S Yonatan, N Murali, M Tulu Wegayehu, SJ Margarette, and K Samatha. "Influence of Cu-Cr Substitution on Structural, Morphological, Electrical and Magnetic Properties of Magnesium Ferrite."Results in physics 8 (2018): 772-79.
Kadam, Ramkrishna H, AsifKarim, Ankush B Kadam, Anil S Gaikwad, and Sagar E Shirsath. "Influence of Cr 3+ Substitution on the Electrical and Magnetic Properties of Ni 0.4 Cu 0.4 Zn 0.2 Fe 2 O 4 Nanoparticles."International Nano Letters 2, no. 1 (2012): 28.
Bayoumy, WA and MA Gabal. "Synthesis Characterization and Magnetic Properties of Cr-Substituted NicuznNanocrystallineFerrite."Journal of Alloys and Compounds 506, no. 1 (2010): 205-09.
Haralkar, SJ, RH Kadam, SS More, Sagar E Shirsath, ML Mane, Swati Patil, and DR Mane. "Substitutional Effect of Cr3+ Ions on the Properties of Mg–Zn Ferrite Nanoparticles."Physica B: Condensed Matter 407, no. 21 (2012): 4338-46.
Kumar, KatrapallyVijaya, Rapolu Sridhar, and DachepalliRavinder. "Magnetic and Electrical Properties of Cr Substituted Ni Nano Ferrites." Processing and Application of Ceramics 12, no. 1 (2018): 1-7.
Kasap, Safa O. Principles of Electronic Materials and Devices. Vol. 2: McGraw-Hill New York, 2006.
More, SD, CM Kale, AB Shinde, and KM Jadhav. "Role of Cr 3+ Substitution on Electrical and Dielectric Behavior of Cu-Ferrite Nanoparticles."International Journal of Engineering and Advanced Technology ((IJEAT) ISSN: 2249–8958), Issue-2 3 (2013): 177-80.
Kasap, Safa O. Principles of Electronic Materials and Devices. Vol. 2: McGraw-Hill New York, 2006.
Rezlescu, N, E Rezlescu, PD Popa, and L Rezlescu. "Effects of Rare-Earth Oxides on Physical Properties of Li–Zn Ferrite."Journal of Alloys and Compounds 275 (1998): 657-59.
Gul, I.H. and ErumPervaiz. "Comparative Study of NiFe2− XAlxO4 Ferrite Nanoparticles Synthesized by Chemical Co-Precipitation and Sol–Gel Combustion Techniques." Materials research bulletin 47, no. 6 (2012): 1353-61
L.G Van Uitert, J. Chem. Phys. 24(2) 1956.
Downloads
Published
How to Cite
Issue
Section
License
Authors retain copyright and grant the Revista Mexicana de Física right of first publication with the work simultaneously licensed under a CC BY-NC-ND 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
