Synthesis and characterization of graphene oxide as dielectric material for parallel plate capacitor

Authors

  • N. Ice Bili Universitas Negeri Yogyayakarta
  • A. Meliyanti Yogyakarta State University
  • T. Hariyanti Universitas Negeri Yogyakarta
  • Ariswan Universitas Negeri Yogyakarta
  • W. Sunu Brams Dwandaru Universitas Negeri Yogyakarta

DOI:

https://doi.org/10.31349/RevMexFis.70.021005

Keywords:

GO; Dielectric material; Parallel plate capacitor

Abstract

Graphite acts as an electrical conductor due to the delocalization of electrons between the surfaces. Graphene oxide (GO) is produced by using graphite via the Hummers method. Reduced GO (rGO) is a form of GO where the oxygen content has been reduced due to chemical, thermal, and other processes. In this study, we have produced a prototype of capacitors containing the synthesized rGO with variation of the rGO mass, i.e.: 0 g., 0,2 g; and 0,8 g. Than we compare the capacitance values obtained from the capacitors using a multitester. Characterizations of the rGO are conducted using XRD, UV-Vis, and FTIR. The results of the UV-Vis test show peak at a wavelength of 300 nm indicating absorption of rGO. The XRD test shows a transition from GO to rGO in an amorphous phase. Finally, the FTIR tests produce transmittance bands from the functional groups of CO2, CO, and OH. This paper shows that the capacitance values of the capacitor using rGO material is greater than using graphite material. It means that rGO is capable of storing more charges than graphite. The highest capacitance value is obtained for the capacitor with 0.2 g rGO, i.e.: 165,02 µF.

References

J.-S. An et al., Unveiling of interstice-occupying dopant segregation at grain boundaries in perovskite oxide dielectrics for a new class of ceramic capacitors, Energy Environ. Sci. 16 (2023) 1992, https://doi.org/10.1039/D2EE03152C

V. Anju and S. K. Narayanankutty, High dielectric constant polymer nanocomposite for embedded capacitor applications, Materials Science and Engineering: B 249 (2019) 114418, https://doi.org/10.1016/j.mseb.2019. 114418

F. I. Ezema, I. Ahmad, and T. Zhao, Graphene Oxide in Enhancing Energy Storage Devices (CRC Press, 2022)

K.-Y. Chan et al., Tailoring mechanical and electrical properties of graphene oxide film for structural dielectric capacitors, Journal of Power Sources 482 (2021) 229020, https://doi.org/10.1016/j.jpowsour.2020.229020

W. S. B. Dwandaru, L. D. Parwati, and R. I.Wisnuwijaya, Formation of graphene oxide from carbon rods of zinc-carbon battery wastes by audiosonic sonication assisted by commercial detergent, Nanotechnology and Precision Engineering (NPE) 2 (2019) 89

F. Wu et al., Reduced graphene oxide (RGO) modified spongelike polypyrrole (PPy) aerogel for excellent electromagnetic absorption, Journal of Materials Chemistry A 3 (2015) 14358

H. Raza, Graphene nanoelectronics: Metrology, synthesis, properties and applications (Springer Science & Business Media, 2012)

V. Nanjundappa et al., Efficient strategies to produce Graphene and functionalized graphene materials: A review, Applied Surface Science Advances 14 (2023) 100386

D. G. Papageorgiou, I. A. Kinloch, and R. J. Young, Graphene/elastomer nanocomposites, Carbon 95 (2015) 460, https://doi.org/10.1016/j.carbon.2015. 08.055

M. Vazquez-Jaime, et al., Effective removal of arsenic from an aqueous solution by ferrihydrite/goethite graphene oxide composites using the modified Hummers method, Journal of Environmental Chemical Engineering 8 (2020) 104416, https://doi.org/10.1016/j.jece.2020.104416

N. A. Putri and Z. A. I. Supardi, SINTESIS DAN KARAKTERISASI GRAPHENE OXIDE (GO) DARI BAHAN ALAM TEMPURUNG KELAPA, Jurnal Inovasi Fisika Indonesia (IFI) 12 (2023) 47, https://doi.org/10.26740/ifi. v12n2.p47-55

R. Santika, A. Astuti, and S. R. A. Usna, Sintesis dan Karakterisasi Sifat Optik Graphene Oxide dari Limbah Bulu Ayam dengan Metode Liquid Phase Exfoliation, Jurnal Fisika Unand 12 (2023) 227, https://doi.org/10.25077/jfu.12.2.228-234.2023

G. Yasin et al., Exploring the Nickel-Graphene Nanocomposite Coatings for Superior Corrosion Resistance: Manipulating the Effect of Deposition Current Density on its Morphology, Mechanical Properties, and Erosion-Corrosion Performance, Advanced Engineering Materials 20 (2018), https://doi.org/10.1002/adem.201701166

R. Siburian et al., New Route to Synthesize of Graphene Nano Sheets, Oriental Journal of Chemistry 34 (2018) 182, https://doi.org/10.13005/ojc/340120

E. F. Rahayu, B. Budiyono, and H. Hadiyanto, The Effect of Microwave Irradiation on the Synthesis of Graphene from Battery Waste on Capacitance Properties, Periodica Polytechnica Chemical Engineering 67 (2023) 345, https://doi.org/10.3311/PPch.21377

W. Du et al., Pristine graphene for advanced electrochemical energy applications, Journal of Power Sources 437 (2019) 226899, https://doi.org/10.1016/j.jpowsour.2019.226899

S. Sunderrajan, L. R. Miranda, and G. Pennathur, Improved stability and catalytic activity of graphene oxide/chitosan hybrid beads loaded with porcine liver esterase, Preparative Biochemistry Biotechnology 48 (2018) 343, https://doi.org/10.1080/10826068.2018.1446153

M. Sohail et al., Modified and improved Hummer’s synthesis of graphene oxide for capacitors applications, Modern Electronic Materials 3 (2017) 110, https://doi.org/10.1016/j.moem.2017.07.002

F. Deswardani et al., Analisis gugus fungsi pada TiO2/biochar dengan spektroskopi FTIR (Fourier Transform Infrared) [Analysis of functional groups in TiO2/biochar using FTIR (Fourier Transform Infrared) spectroscopy], Journal Online of Physics 5 (2020) 54, https://doi.org/10.22437/jop.v5i2.9397

C. H. Manoratne, S. R. D. Rosa, and I. R. M. Kottegoda, XRDHTA, UV Visible, FTIR and SEM Interpretation of Reduced Graphene Oxide Synthesized from High Purity Vein Graphite, Material Science Research India 14 (2017) 19, https://doi.org/10.13005/msri/140104

G. A. Toader, F. R. Nitu, and M. Ionita, Graphene Oxide/ Nitrocellulose Non-Covalent Hybrid as Solid Phase for Oligo-DNA Extraction from Complex Medium, Molecules 28 (2023) 4599, https://doi.org/10.3390/molecules28124599

Downloads

Published

2024-03-01

How to Cite

[1]
N. I. B. Bili, A. M. Meliyanti, T. H. Hariyanti, A. Ariswan, and W. S. B. D. Dwandaru, “Synthesis and characterization of graphene oxide as dielectric material for parallel plate capacitor”, Rev. Mex. Fís., vol. 70, no. 2 Mar-Apr, pp. 021005 1–, Mar. 2024.