A scientific journal publishing original research and reviews across all areas of physics, serving the international physics community.
Editor-in-chief: Ramón Castañeda Priego
Frequency: Bimonthly
Publisher: Sociedad Mexicana de Física
En este trabajo, se realizó un análisis cuantitativo de los metales pesados Cr y Cu en sedimentos fluviales mediante espectroscopia de ruptura inducida por láser (LIBS) para evaluar el antropogénico. Para realizar el análisis, se recolectaron diferentes muestras de sedimento en las posiciones seleccionadas. Se construyeron curvas de calibración de adición estándar para Cr y Cu midiendo la línea Cr I a 357.87 nm y la línea Cu I a 324.75 nm. Los contenidos de humedad y materia orgánica de los sedimentos fueron tomados en cuenta para superar el efecto matriz. Los modelos cuantitativos se evaluaron estadísticamente para evaluar la robustez y la capacidad de predicción del método. Los valores bajos de la raíz - medias - errores cuadrados para la calibración ( RMSEC ), la predicción ( RMSEP ) y la validación cruzada (RMSECV ) se calcularon. Se obtuvieron valores altos de los coeficientes de correlación de calibración ( R 2 c = 0.984 para Cr; R 2 c = 0.986 para Cu) y validación cruzada ( R 2 cv = 0.985 para Cr; R 2 cv = 0.981 para Cu). Los límites de detección calculados ( LoD ) fueron 2.9 ppm para Cr y 3.3 ppm para Cu, y los límites de cuantificación ( LoQ) fueron 9.5 ppm para Cr y 11 ppm para Cu. Las concentraciones de Cr y Cu superiores a los valores de referencia se obtuvieron en los sedimentos aguas abajo (Cr: 49 ppm, Cu: 81 ppm) que son indicativos de la contaminación de la cuenca por metales pesados debido al derrame de efluentes no tratados derivados de actividades antropogénicas. . El análisis LIBS se optimizó para el monitoreo confiable de metales pesados en sedimentos fluviales.
Many studies, focused in TiO2 nanotubes obtained by anodization, uses frequently a NH4F salt concentration from 0.3 – 0.5 wt% and the information about how voltage and time affects to nanotubes morphology, are valid for these concentration, moreover, this range induces a long time of anodized. TiO2 nanotubes were prepared by anodization process of a set of titanium foils in order to study the influence of time and voltage on the morphology of them. The anodization process consists of an organic media of ethylene glycol and 1.2 wt% of NH4F salts, voltage from 5 to 30 V for a time period from 1 to 6 hours, constant potential of 30 V for a time lapse from 10 to 360 minutes and 5 to 480 seconds. All anodized samples are rinsed and annealed to 400 °C by 3 hours to obtain an anatase crystalline structure. The morphological characterization was carried out by Field Emission Scanning Electron Microscopy (FESEM) to verify the presence of the nanostructures: nanopores, nanotubes and nanograss, these nanostructures were identified to appear for a time period from 5 to 480 seconds, 10 to 60 minutes and 1 to 6 hours, respectively. The surface morphology, inner diameter and length of the nanotubes varied with the electrochemical anodization parameters. Raman spectroscopy was used for optical characterization in order to identify the changes in signal intensity and Eg mode Shift and it was observed that intensity suffers an increment and Eg mode suffers a blue shift as a thickness function.
The electrospinning technique has been used to synthesize TiO2 nanofibres, which by annealing at high temperatures in a wide range achieves the crystal phase transformation of anatase to rutile passing through the anatase+rutile mixed. The investigated temperature range was 0-1000°C. The TiO2 nanofibres chemical stoichiometry and surface morphology were obtained by Scanning Electron Microscopy and Energy Dispersive Spectrometry. The nanofibres diameter was ranged from 137.0 to 115.3 nm in the annealing temperature interval of 0-1000°C. The influence of the annealing temperature on the structure and crystal phase quality of the TiO2crystal has been investigated by X-ray diffraction and Raman scattering. Clear evidence of nanofibres structural transformation from pure anatase to pure rutile structures, including the quasi-amorphous and anatase+rutile mixed phases has been confirmed by Raman scattering. By X-ray diffraction was found that the nanofibres crystalline phases present as preferential growth direction (101) for anatase and (110) for rutile. The Raman spectroscopy exhibits the anomalous behaviour for band broadening and shifting of Raman bands with increasing crystallite size that form the nanofibres. The room-temperature photoluminescence presents radiative bands whose main band redshifts, from 2.56 to 1.32 eV, as the crystalline phase transforms in the investigated annealing temperature range.
Structural, elastic, electronic and magnetic properties of the quaternary Heusler alloys are calculated using the full-potential linearized augmented plane wave (FP-LAPW) method in the framework of the density functional theory (DFT) and implemented in WIEN2k code. The exchange-correlation potential is evaluated using the generalized gradient approximation (GGA) within the Perdew-Burke-Ernzerhof (PBE) parameterization. Our theoretically results provide predictions for the mixed in which no experimental and theoretical data are currently available. The lattice parameter and bulk modulus as well the elastic constants and their related elastic moduli for have been calculated. Also, the electronic properties including density of states and band structures indicate the metallic character for . Morever, this quaternary Heusler alloy is found to be ferromagnetic, ductile and anisotropic in nature.
The new ordered vacancy compound Ag3In5Te9 was synthesized by the melt and annealing technique and its structure was refined from X-ray powder diffraction pattern using the Rietveld method. The title compound crystallizes in the tetragonal space group P 2c (Nº 112), with a = 6.3453(2) Å, c = 12.5754(7) Å, V = 506.32(4) Å3. The refinement of 23 instrumental and structural parameters led to Rp = 5.4%, Rwp = 5.8%, Rexp = 5.1 %, S = 1.1. This ternary compound is isostructural with Cu3In5Te9 and have a defect adamantane structure.
This pagination specifies the characteristics of Carreau nano-fluid model embedded with hydro-magnetic (MHD) effects and the energy equation is extracted through Cattaneo-Christov approach. The process of heat generation and chemical reaction are also carried out whereas the fluid flow having infinite shear rate viscosity is induced by the stretching sheet. The mathematical form is developed in order to get the coupled partial differential equations and admissible similarity transforms are used to construct the set of ordinary differential equations and then sorted out numerically by applying Runge-Kutta Fehlberg method supported with shooting scheme. The graphs are plotted that portrays the impact of fluid velocity and temperature towards various engineering parameters which reveals that the fluid temperature increases when enlarging heat generation parameter. The validations for the numerical values of skin friction coefficient are delineated with the existing literature [33]. Also, the numerical findings for the local Nusselt number are offered.
Abstract. Two identical homemade prototypes are used to monitoring the tide levels on two strategic points of the Serinhaém estuary. This monitoring was realized along a period close to the new moon phase. From the analysis of the experimental results, the average height of the tide is determined between each period of high-tide and low-tide. These estimations show discrepancies minors than half order of magnitude, compared to the theoretical predictions of the static and dynamic oceanic tide models. Also the amplification effects of the tide in the estuary head can be quantified exhibiting a maximum gain 1.33, which is observed in the new moon phase.
Mathematically, the sphere unit S² is described to be a 2-sphere in an ordinary space with a positive curvature. In this study, we aim to present the manipulation of a spherical charged particle in a continuous motion with a magnetic field on the sphere S² while it is exposed to a frictional force. In other words, we effot to derive the exact geometric characterization for the spherical charged particle under the influence of a frictional force field on the unit 2-sphere. This approach also helps to discover some physical and kinematical characterizations belonging to the particle such as the magnetic motion, the torque, the potential energy functional, and the Poynting vector.
In this paper, the generalized exponential rational function method (GERFM) and the extended sinh-Gordon equation expansion method (ShGEEM) are used to construct exact solutions of the perturbed β-conformable-time Radhakrishnan-Kundu-Lakshmanan (RKL) equation. This model governs soliton propagation dynamics through a polarization-preserving fiber.
Fractional derivatives are described in the β-conformable sense. As a result, we get new form of solitary traveling wave solutions for this model including novel soliton, traveling waves and kink-type solutions with complex structures. Physical interpretations of some extracted solutions are also included through taking suitable values of parameters and derivative order in them. It is proved that these methods are powerful, efficient, and can be fruitfully implemented to establish new solutions of nonlinear conformable-time partial differential equations applied in mathematical physics.
In this paper, the time fractional Kolmogorov-Petrovskii-Piskunov (FKP) equation is analyzed by means of Lie symmetry approach. The FKP is reduced to ordinary differential equation of fractional order via the attained point symmetries. Moreover, the simplest equation method is used in construct the exact solutions of underlying equation with recently introduced conformable fractional derivative.
The deposition of a high resistivity transparent (HRT) oxide between a transparent conductive oxide (TCO) and the window CdS has demonstrated the improvement of performance of CdS/CdTe solar cells, fabricated in the superstrate-configuration. In this work the influence of the pneumatic spray pyrolysis (PSP) and magnetron sputtering techniques on the properties TCO/SnO2/CdS structure through the deposition of the intermediate SnO2 between the commercial conducting glass and CdS window is presented by means of X-ray photoelectron spectroscopy (XPS), secondary ion mass spectroscopy (SIMS), and contact resistance, calculated using transmission line method (TLM), in order to reduce the front contact resistance in devices with superstrate-configuration. The results of this work are applicable to other solar cells in the same configuration as the recent solar cells based on the compound Sb2Se3, where the use of this type of HRT has not been studied.
Rev. Mex. Fis. 65 (5) 2019
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REVISTA MEXICANA DE FÍSICA, year 72, issue 2, March-April 2026. Bimonthly Journal published by Sociedad Mexicana de Física, A. C. Departamento de Física, 2º Piso, Facultad de Ciencias, Universidad Nacional Autónoma de México, Ciudad Universitaria, Alcaldía Coyacán, C.P. 04510, Ciudad de México. Apartado Postal 70-348. Tels. (+52)55 5622 4946, (+52) 5622 4848, https://rmf.smf.mx/ojs/rmf, e-mail: rmf@ciencias.unam.mx. Chief Editor: Ramón Castañeda Priego. INDAUTOR Certificate of Reserve: 04-2021-102913424600-203, e-ISSN: 2683-2224, granted by Instituto Nacional del Derecho de Autor. Responsible for the last update of this issue, Technical Staff of Sociedad Mexicana de Física, A. C., 2o. Piso, Facultad de Ciencias, Universidad Nacional Autónoma de México, Ciudad Universitaria, C.P. 04510, Coyoacán, CDMX. Date of last modification, March 9, 2026.
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