Zeolitas Na-A4 como anfitrión de nanopartículas de PbS

Abstract

In this work we report the optical and structural properties of composite materials based on the semiconductor PbS enclosed in type A zeolite. The composite materials were obtained by chemical reaction in several steps of the zeolite in alkaline aqueous solutions containing de Pb$^{2 + }$ and S$^{2 - }$ions successively. Three samples were prepared at temperatures of 40, 50 and 60$^\circ$C during the chemical reaction with S$^{2 - }$ions. The obtained materials were studied by x-ray diffraction, scanning and transmission electron microscopy, diffuse reflectance spectroscopy and photoluminescence. The experimental results show the formation of spherical-shaped PbS particles with nanometric size and cubic crystalline structure embedded in the zeolite matrix. The absorption spectra of the samples display a well defined absorption band at about 300 nm due to the PbS nanoparticles in the zeolite matrix. In addition, an absorption peak appears in the absorption spectra at about 400 nm assigned to exciton transitions.