Adsorption-desorption kinetics with multiple site occupation

Authors

  • S. Manzi
  • G. Costanza
  • V.D. Pere
  • ra.

Keywords:

Models of surface kinetics, adsorption kinetics, surface diffusion, termal desorption spectroscopy

Abstract

The adsorption-desorption kinetics with multiple site occupation in a one-dimensional network is formulated in the framework of the kinetic lattice gas model. The kinetic equations that describe the time evolution of the correlators are obtained by use of the so called Local Evolution Rules, that take into account the adsorption, desorption, and diffusion of the adsorbed molecules. After truncating the infinite hierarchy of equations, different cases are analyzed. Equilibrium solutions are obtained and the exact expression for adsorption isotherms as well as the nearest-neighbor correlations are presented. The asymptotic approach to the equilibrium is also discussed. Finally, we analyzed the desorption kinetics throughout the thermal desorption spectra.

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Published

2005-01-01

How to Cite

[1]
S. Manzi, G. Costanza, V. Pere, and ra., “Adsorption-desorption kinetics with multiple site occupation”, Rev. Mex. Fís., vol. 51, no. 1, pp. 14–0, Jan. 2005.

Issue

Vol. 51 No. 1 (2005): Revista Mexicana de Física.

Section

Articles

License

Authors retain copyright and grant the Revista Mexicana de Física right of first publication with the work simultaneously licensed under a CC BY-NC-ND 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.